Publications

Researcher ID       ORCID

Selected pubications

“Characterization and reactivity studies on a terminal copper-nitrene species”
Teresa Corona, Lídia Ribas, Mireia Rovira, Erik R. Farquhar, Xavi Ribas,* Kallol Ray,* Anna Company*
Angew. Chem. Int. Ed. 2016, 55, 14005-14008. Selected as “Hot paper”.
http://onlinelibrary.wiley.com/doi/10.1002/anie.201607238/abstract

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“Rapid hydrogen and oxygen atom transfer by a high-valent nickel-oxygen species”
Teresa Corona, Apparao Draksharapu, Sandeep K. Padamati, Ilaria Gamba, Vlad Martin-Diaconescu, Ferran Acuña-Parés, Wesley R. Browne, Anna Company*
J. Am. Chem. Soc. 2016, 138, 12987-12996
http://pubs.acs.org/doi/abs/10.1021/jacs.6b07544

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Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention”
Joan Serrano-Plana, Williamson N. Oloo, Laura Acosta-Rueda, Katlyn K. Meier, Begoña Verdejo, Enrique García-España, Manuel G. Basallote,* Eckard Münck,* Lawrence Que, Jr.,* Anna Company,* Miquel Costas*
J.
 Am. Chem. Soc. 2015137, 15833–15842.
http://pubs.acs.org/doi/abs/10.1021/jacs.5b09904

ja-2015-099047_0008

 

 

“Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with bis(μ-oxo)dicopper(III) species”
Joan Serrano-Plana, Isaac Garcia-Bosch, Riosuke Miyake, Miquel Costas*, Anna Company*
Angew. Chem. Int. Ed. 2014, 53, 9608-9612.
http://onlinelibrary.wiley.com/doi/10.1002/ange.201405060/abstract

TOC

 

Full list of publications

56. Joan Serrano-Plana, Ferran Acuña-Parés, Valeria Dantignana, Williamson N. Oloo, Esther Castillo, Apparao Draksharapu, Christopher J. Whiteoak, Vlad Martin-Diaconsescu, Manuel G. Basallote,* Josep M. Luis,* Lawrence Que Jr.,* Miquel Costas,* Anna Company* “Acid-triggered O–O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C–H bonds” Accepted in Chem. Eur. J. DOI: 10.1002/chem.201704851

55. Valeria Dantignana, Michela Milan, Anna Company,* Massimo Bietti,* Miquel Costas* “Chemoselective Aliphatic C−H Bond Oxidation Enabled by Polarity Reversal” Accepted in ACS Central Sci.

54. Carla Magallón, Joan Serrano-Plana, Steven Roldán-Gómez, Xavi Ribas, Miquel Costas, Anna Company* “Preparation of a coordinatively saturated m-h2:h2-peroxodicopper(II) compound” Inorg. Chim. Acta, DOI: 10.1016/j.ica.2017.08.061

53.  Teresa Corona, Sandeep K. Padamati, Ferran Acuña-Parés, Carole Duboc, Wesley R. Browne, Anna Company* “Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2Chem. Commun. 2017, 53, 11782-11785.

52. Oriol Planas, Steven Roldán-Gómez, Vlad Martin-Diaconescu, Teodor Parella, Josep M. Luis, Anna Company, Xavi Ribas* “Carboxylate-asssited formation of aryl-Co(III) masked-carbenes in cobalt-catalyzed C-H functionalization with diazo esters” J. Am. Chem. Soc. 2017, 139, 14649-14655.

51. Mireia Rovira, Steven Roldán-Gómez, Vlad Martin-Diaconescu, Christopher J. Whiteoak, Anna Company, Josep M. Luis, Xavi Ribas “Trifluoromethylation of a well-defined square planar aryl-Ni(II) complex involving Ni(III)/CF3• and Ni(IV)-CF3 intermediate species” Chem. Eur. J. 2017, 23, 11662-11668. Selected as “Hot Paper”.

50. Elise Bernoud, Anna Company, Xavi Ribas* “Direct use of CO2 for O-arylcarbamate synthesis via mild Cu(II)-catalyzed aerobic C-H functionalization in pincer-like macrocyclic systems” J. Organomet. Chem. 2017, 845, 44-48.

49. Patrick Holze, Teresa Corona, Nicolas Frank, Betarice Braun-Cula, Christian Herwig, Anna Company, Christian Limberg* “Activation of O2 at a lewis acidic nickel(II) complex – characterization of a metaestable organoperoxide complex” Angew. Chem. Int. Ed. 201756, 2307-2311

48. Oriol Planas, Christopher Whiteoak, Vlad Martin-Diaconescu, Ilaria Gamba, Josep M. Luis, Teodor Parella, Anna Company, Xavi Ribas* “Isolation of Key Organometallic Aryl-Co(III) Intermediates in Co-Catalyzed C(sp2)-H Functionalizations and New Insights into Alkyne Annulation Reaction Mechanisms” J. Am. Chem. Soc. 2016, 138, 14388-14397.

47. Teresa Corona, Lídia Ribas, Mireia Rovira, Erik R. Farquhar, Xavi Ribas,* Kallol Ray,* Anna Company* “Characterization and reactivity studies on a terminal copper-nitrene species” Angew. Chem. Int. Ed. 2016, 55, 14005-14008. Selected as “Hot paper”.

46. Teresa Corona, Apparao Draksharapu, Sandeep K. Padamati, Ilaria Gamba, Vlad Martin-Diaconescu, Ferran Acuña-Parés, Wesley R. Browne, Anna Company* “Rapid hydrogen and oxygen atom transfer by a high-valent nickel-oxygen species” J. Am. Chem. Soc. 2016, 138, 12987-12996.

45. Teresa Corona, Anna Company* “Nitrous oxide activation by a cobalt(II) complex for aldehyde oxidation under mild conditions” Dalton Trans. 2016, 45, 14530-14533.

44. Teresa Corona, Anna Company* “Well-defined spectroscopically trapped mononuclear nickel-oxygen species” Chem. Eur. J. 2016, 22, 13422-13429.

43. Mayank Puri, Anna Company, Gerard Sabenya, Miquel Costas,* Lawrence Que, Jr.* “Oxygen-Atom Exchange Between H2O and Nonheme Oxoiron(IV) Complexes: Ligand Dependence and Mechanism” Inorg. Chem.201655, 5818–5827.

42. Joan Serrano-Plana, Almudena Aguinaco, Raquel Belda, Enrique García-España, Manuel G. Basallote,* Anna Company,* Miquel Costas* “Exceedingly fast oxygen atom transfer to olefins by a catalytically competent nonheme iron species” Accepted in Angew. Chem. Int. Ed. 2016, 55, 6310-6314. Selected as “Hot paper”

41. Christopher J. Whiteoak,* Oriol Planas, Anna Company, Xavi Ribas* “Access to 5- and 7-Nitro-8-aminoquinolines through a Novel Room-Temperature Cobalt-Catalyzed Remote Nitration Protocol” Adv. Synth. Catal. 2016, 358, 1679-1688.

40. Joan Serrano-Plana, Williamson N. Oloo, Laura M. Acosta, Kathlyn K. Meier, Manuel G. Basallote,* Eckard Münck,* Lawrence Que Jr.,* Anna Company,* Miquel Costas* “An iron(III)-peroxide that selectively oxygenates strong C-H bonds with stereoretention at very fast rates” J. Am. Chem. Soc. 2015, 137, 15833-15842.

39. Marta Soler, Eduard Figueras, Joan Serrano-Plana, Marta González-Bártulos, Anna Massaguer, Anna Company, Ma Ángeles Martínez, Jaroslav Malina, Viktor Brabec,* Lidia Feliu,* Marta Planas,* Xavi Ribas,* Miquel Costas* “Design, Preparation, and Characterization of Zn and Cu Metallopeptides Based On Tetradentate Aminopyridine Ligands Showing Enhanced DNA Cleavage Activity” Inorg. Chem. 2015, 54, 10542-10558.

38. Oriol Planas, Christopher J. Whiteoak,* Anna Company, Xavi Ribas* “Regioselective access to sultam motifs through cobalt-catalyzed annulation of aryl sulfonamides and alkynes using an 8-aminoquinoline directing group” Adv. Synth. Catal. 2015, 357, 4003-4012.

37. Teresa Corona, Florian Pfaff, Ferran Acuña-Parés, Apparao Draksharapu, Julio Lloret-Fillol, Wesley R. Browne, Kallol Ray, Anna Company* “Reactivity of a nickel(II) bis(amidate) complex with meta-chloroperbenzoic acid: formation of a potent oxidizing species” Chem. Eur. J. 2015, 21, 15029-15038.

36. Verònica Postils, Anna Company, Miquel Solà,* Miquel Costas,* Josep M. Luis* “Computational Insight into the Alkane-Hydroxylation Mechanism by Non-Heme Fe(Pytacn) Iron Complexes. Effect of the Substrate and Solvent” Inorg. Chem. 2015, 54, 8223-8236.

35. Joan Serrano-Plana, Isaac Garcia-Bosch, Anna Company,* Miquel Costas* “Exploration of Synergistic Effects in O2 Binding and Activation Paths with Coordination Complexes that Model Structural and Reactivity Aspects of Copper Oxygenases” Acc. Chem. Res. 2015, 48, 2397-2406.

34. Joan Serrano-Plana, Miquel Costas,* Anna Company* “Building complexity in O2-binding copper complexes. Site-selective metallation and intermolecular O2-binding at dicopper and heterometallic complexes derived from an unsymmetric ligand” Inorg. Chem. 2014, 53, 12929-12938.

33. Oriol Planas, Martin Clémancey, Jean-Marc Latour, Anna Company,* Miquel Costas* “Structural Modeling Iron Halogenases: Synthesis and Reactivity of Halide-Iron(IV)-oxo Compounds” Chem. Commun. 2014, 50, 10887-10890.

32. Joan Serrano-Plana, Isaac Garcia-Bosch, Ryosuke Miyake, Miquel Costas,* Anna Company* “Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with bis(m-oxo)dicopper(III) species” Angew. Chem. Int. Ed. 2014, 53, 9608-9612.

31. Anna Company,* Gerard Sabeña, María González-Béjar, Laura Gómez, Martin Clémancey, Geneviève Blondin, Andrew J. Jasniewski, Mayank Puri, Wesley R. Browne, Jean-Marc Latour, Lawrence Que Jr., Miquel Costas, Julia Pérez-Prieto,* Julio Lloret-Fillol* “Triggering the generation of an iron(IV)-oxo compound and its reactivity towards sulfides by RuII photocatalysis” J. Am. Chem. Soc. 2014, 136, 4624-4633.

30. Maite Canals, Rafael Gonzalez-Olmos,* Miquel Costas,* Anna Company* “Robust iron coordination complexes with N-based neutral ligands as efficient Fenton-like catalysts at neutral pH” Environ. Sci. Technol. 2013, 47, 9918-9927

29. Irene Prat, Anna Company,* Teresa Corona, Teodor Parella, Xavi Ribas, Miquel Costas* “Assessing the Impact of Electron Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the Fe(Pytacn) family of complexes” Inorg. Chem. 2013, 52, 9229-9244.

28. Irene Prat, Anna Company,* Verònica Postils, Xavi Ribas, Lawrence Que Jr., Josep M. Luis,* Miquel Costas* “The Mechanism of Stereospecific C-H Oxidation by Fe(PyTACN) Complexes. Bioinspired Non Heme Iron Catalysts Containing cis-Labile Exchangeable Sites” Chem. Eur. J. 2013, 19, 6724-6738.

27. Irene Prat, David Font, Anna Company, Kathrin Junge, Xavi Ribas, Matthias Beller,* M. Costas* “Fe(PyTACN)-catalyzed cis-dihydroxylation of Olefins with H2O2Adv. Synth. Catal. 2013, 355, 947-956.

26. Michael Haberberger, Chika I. Someya, Anna Company, Elisabeth Irran, Stephan Enthaler* “Application of a Nickel-bispidine complex as Pre-catalysts for C(sp2)–C(sp3) Bond Formations” Catal. Lett. 2012, 142, 557-565.

25. Subrata Kundu, Eduard Matito, Stephan Walleck, Florian F. Pfaff, Florian Heims, Battist Rabay, Josep M. Luis, Anna Company, Beatrice Braun, Thorsten Glaser, Kallol Ray* “O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core” Chem. Eur. J. 2012, 18, 2787-2791.

24. Stephan Enthaler,* Anna Company* “Palladium-catalysed hydroxylation and alkoxylation” Chem. Soc. Rev. 2011, 40, 4912-4924.

23. Isaac Garcia-Bosch, Anna Company, Clyde W. Cady, Stenbjörn Styring, Wesley R. Brown, Xavi Ribas, Miquel Costas “Evidence for a Precursor Complex in C-H Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex” Angew. Chem. Int. Ed. 2011, 50, 5648-5653. Selected as “VIP Paper”.

22. Sebastian Krackl, Anna Company, Stephan Enthaler,* Matthias Driess* “Low-Valent Molybdenum-Based Dual Pre-Catalysts for Highly Efficient Catalytic Epoxidation of Alkenes and Deoxygenation of Sulfoxides” ChemCatChem 2011, 3, 1186-1192.

21. Sebastian Krackl, Anna Company, Yilmaz Aksu, David Avnir,* Matthias Driess* “Entrapment of Heteropoly Acids in Metallic Silver Matrices: Unique Heterogenized Acid Catalysts” ChemCatChem 2011, 3, 227-232.

20. Anna Company, Irene Prat, Jonathan R. Frisch, Rubén Mas-Ballesté, Mireia Güell, Gergely Juhász, Xavi Ribas, Eckard Münck,* Josep M. Luis,* Lawrence Que Jr,* Miquel Costas* “Modelling the cis-oxo-labile binding site motif of non-heme iron oxygenases. Water exchange and remarkable oxidation reactivity of a novel non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand” Chem. Eur. J. 2011, 17, 1622-1634.

19. Shenglai Yao, Christian Herwig, Yun Xiong, Anna Company, Eckhard Bill, Christian Limberg,* Matthias Driess* “Monooxygenase-Like Reactivity of an Unprecedented, Heterobimetallic FeO2Ni Moiety” Angew. Chem. Int. Ed. 2010, 49, 7054-7058. Selected as “Hot Paper”.

18. Anna Company, Shenglai Yao, Kallol Ray, Matthias Driess* “Dioxygenase-like Reactivity of an Isolable Superoxo-Nickel(II) Complex” Chem. Eur. J. 2010, 16, 9669-9675.

17. Isaac Garcia-Bosch, Anna Company, Jonathan R. Frisch, Miquel Torrent-Sucarrat, Mar Cardellach, Ilaria Gamba, Mireia Güell, Luigi Casella,* Lawrence Que Jr,* Xavi Ribas,* Josep M. Luis,* Miquel Costas* “O2 Activation and Selective Phenolate ortho Hydroxylation by an Asymmetric Dicopper m-h1:h1-peroxido Complex” Angew. Chem. Int. Ed. 2010, 49, 2406-2408. Selected as “Hot Paper”.

16. Laura Gómez, Isaac Garcia-Bosch, Anna Company, Jordi Benet-Buchholz, Alfons Polo, Xavier Sala, Xavi Ribas,* Miquel Costas* “Stereospecific C-H Oxidation with H2O2 Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst” Angew. Chem. Int Ed. 2009, 48, 5720 – 5723.

15. Priyabrata Banerjee, Anna Company, Thomas Weyhermüller, Eckhard Bill, Corinna R. Hess* “Zn and Fe Complexes Containing a Redox Active Macrocyclic Biquinazoline Ligand” Inorg. Chem. 2009, 48, 2944 – 2955.

14. Anna Company, Yan Feng, Mireia Güell, Xavi Ribas, Josep M. Luis, Lawrence Que Jr,* Miquel Costas* “Olefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations” Chem. Eur. J. 2009, 15, 3359 – 3362.

13. Isaac Garcia-Bosch, Anna Company, Xavier Fontrodona, Xavi Ribas,* Miquel Costas* Efficient and Selective Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Catalyst” Org. Lett. 2008, 10, 2095 – 2098. Selected by Synfacts 2008, 8, 866 – 866.

12. Anna Company, Laura Gómez, Xavier Fontrodona, Xavi Ribas, Miquel Costas* A Novel Platform for Modeling Oxidative Catalysis in Non-Heme Iron Oxygenases with Unprecedented Efficiency” Chem. Eur. J. 2008, 14, 5727 – 5731.

11. Anna Company, Sara Palavicini, Isaac Garcia-Bosch, Rubén Mas-Ballesté, Lawrence Que Jr, Elena V. Rybak-Akimova,* Luigi Casella,* Xavi Ribas, Miquel Costas* Tyrosinase-Like Reactivity in a CuIII2(µ-O)2 Species” Chem. Eur. J. 2008, 14, 3535 – 3538.

10. Anna Company, Nans Roques, Mireia Güell, Veronica Mugnaini, Laura Gómez, Inhar Imaz, Angela Dactu, Miquel Solà, Josep M. Luis, Jaume Veciana,* Xavi Ribas,* Miquel Costas* “Nanosized trigonal prismatic and antiprismatic CuII coordination cages based on tricarboxylate linkers” Dalton Tans. 2008, 1679 – 1682.

9. Anna Company, Laura Gómez, Mireia Güell, Xavi Ribas, Josep M. Luis, Lawrence Que Jr,* Miquel Costas* “Alkane Hydroxylation by a Nonheme Iron Catalyst that Challenges the Heme Paradigm for Oxygenase Action” J. Am. Chem. Soc. 2007, 129, 15766 – 15767.

8. Laura Gómez, Isaac Garcia-Bosch, Anna Company, Xavier Sala, Xavier Fontrodona, Xavi Ribas, Miquel Costas* “Chiral Manganese Complexes with Pinene Appended Tetradentate Ligands as Stereoselective Epoxidation Catalysts” Dalton Trans. 2007, 5539-5545.

7. Anna Company, Joo-Eun Jee, XaviRibas, Josep M. Lopez-Valbuena, Laura Gómez, Montserral Corbella, Antoni Llobet,* José Mahía, Jordi Benet-Buchholz, Miquel Costas,* Rudi van Eldik* “Structural and Kinetic Study of Reversible CO2 Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes” Inorg. Chem. 2007, 46, 9098 – 9110.

6. Laura Gómez, Anna Company, Xavier Fontrodona, Xavi Ribas,* Miquel Costas* “Self-Assembling of Nanoscopic Molecular Rectangles, Extended Helicates and Porous-like Materials Based on Macrocyclic Dicopper Building Blocks Under Fine Supramolecular Control” Chem. Commun. 2007, 42, 4410 – 4412.

5. Anna Company, Laura Gómez, Rubén Mas-Ballesté, Ivan V. Korendovych, Xavi Ribas, Albert Poater, Teodor Parella, Xavier Fontrodona, Jordi Benet-Buchholz, Miquel Solà, Lawrence Que Jr,* Elena V. Rybak-Akimova,* Miquel Costas* “Fast O2 Binding at Dicopper Complexes Containing Schiff-Base Dinucleating Ligands” Inorg. Chem. 2007, 46, 4997 – 5012.

4. Anna Company, Mireia Güell, Dana Popa, Jordi Benet-Buchholz, Teodor Parella, Xavier Fontrodona, Antoni Llobet, Miquel Solà, Xavi Ribas, Josep M. Luis,* Miquel Costas* “A Red-ox Controlled Molecular Flipper Motor Based on a Chiral Cu Complex” Inorg. Chem. 2006, 45, 9643 – 9645.

3. Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V, Rybak-Akimova,* Lawrence Que Jr, Xavier Fontrodona, Teodor Parella, Antoni Llobet, Miquel Costas* “O2 Chemistry of Dicopper Complexes with Alkyltriamine Ligands. Comparing Synergistic Effects on O2 Binding” Inorg. Chem. 2006, 45, 5239 – 5241.

2. Miquel Costas,* Xavi Ribas, Albert Poater, Josep M. López Valbuena, Raül Xifra, Anna Company, Miquel Duran, Miquel Solà,* Antoni Llobet,* Montserrat Corbella, Miguel Angel Usón, José Mahía, Xavier Solans, Xiaopeng Shan, Jordi Benet-Buchholz “Copper(II) Hexaaza Macrocyclic Binuclear Complexes Obtained from the Reaction of Their Copper(I) Derivates and Molecular Dioxygen” Inorg. Chem. 2006, 45, 3569 – 3581

1. Anna Company, Laura Gómez, Josep M. López Valbuena, Rubén Mas-Ballesté, Jordi Benet-Buchholz, Antoni Llobet,* Miquel Costas* “Isomeric Molecular Rectangles Resulting from Self-Assembly of Dicopper Complexes of Macrocyclic Ligands” Inorg. Chem. 2006, 45, 2501 – 2508.

Book chapters

5. A. Company, J. Lloret-Fillol, M. Costas “Small Molecule Models for Nonporphyrinic Iron and Manganese Oxygenases”. Chapter in the encyclopedia “Comprehensive Inorganic Chemistry II, Vol. 3” Oxford: Elsevier, 2013. Editors: Jan Reedijk and Kenneth Poeppelmeier.

4. A. Company, M. Costas “Selective Alkane Oxidation” Chapter in the book entitled “Applied Homogeneous Catalysis with Organometallic Compounds. A Comprehensive Handbook in Three Volumes, 3/e” Weinheim: Wiley-VCH Verlag. Editor: Matthias Beller. Accepted.

3. A. Company, J. Lloret, L. Gómez, M. Costas “Alkane C-H Oxidation Catalyzed by Transition Metal Complexes” Chapter in the book entitled “Alkane C-H Activation by Single-Site Metal Catalysis”. Dortdrecht: Springer, 2012. Editor: Pedro J. Pérez.

2. A. Company, L. Gómez, M. Costas “Bioinspired Non-heme Iron Catalysts in C-H and C=C Oxidation Reactions” Chapter in the book entitled “Iron-containing enzymes: versatile catalysts of hydroxylation reactions in nature”. Cambridge: RSC Publishing, 2011. Editor: Sam P. de Visser and Devesh Kumar.

1. A. Company “O2 Reactivity at Model Copper Systems: Mimicking Tyrosinase Reactivity” Chapter in the book entitled “Ideas in Chemistry and Molecular Sciences: Where Chemistry Meets Life”. Weinheim: Wiley-VCH Books, 2010. Editor: Bruno Pignataro.

Patents

5. Ribas, M. Costas, C. García-Simón, A. Company, L. Gómez “Nanocajas moleculares para la separación selectiva de fulerenos” Application: P201430315, Spain. Application date: 07/03/2014

4. Ribas, M. Costas, O. Cussó, A. Company, J. Lloret, M. Sánchez, C. Martín, M. J. Rosales, F. Olmos “Complejos metálicos que comprenden compuestos poliamínicos y dichos compuestos para su uso como agentes antiparasitarios” Application: P201331559, Spain. Application date: 23/10/2013

3. Ribas, M. Costas, O. Cussó, A. Company, J. Lloret, M. Sánchez, C. Martín, M. J. Rosales, F. Olmos “Complejos poliamínicos y complejos metálicos que los comprenden para su uso como agentes antiparasitarios” Application: P201331558, Spain. Application date: 23/10/2013

2. Cussó, D. Font, L. Gómez, I. Garcia-Bosch, I. Prat, A. Company, J. Lloret-Fillol, X. Ribas, M. Costas “Catalizadores para la epoxidación de alquenos” Application: P201231746, Spain. Application date: 13/11/2012

1. Ribas, M. Costas, I. Garcia-Bosch, A. Company, L. Gómez “Catalizadores de manganeso y su uso para la epoxidación selectiva de olefinas” Application: P200801081, Spain. Application date: 18/04/2011

 

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